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Table 1. Properties of NMR Probe Metallic Materials at 300 K
Table 2. Properties of NMR Probe Dielectric Materials at 300 K
Table 3. Composition of Selected NMR Probe Materials
Properties of NMR Probe Metallic Materials at 300 K
Material |
Dens. |
Youngs mod |
Solidus Temp |
Yield strength |
Elong.
|
Elect. cond. |
Therm. cond. |
Therm. expan. |
Spec. heat |
Magn. suscept. |
Symbol |
d |
E |
TM |
S |
δ |
σ |
kT |
bT |
CP |
χV |
Units |
kg/m3 |
GPa |
°C |
MPa |
% |
M(Ωm)-1 |
W/mK |
10-6 /K |
J/kgK |
10-6 |
Aluminum |
2,700 |
69 |
660 |
30 |
25 |
36.6 |
230 |
22 |
900 |
20.9 |
Chromium |
7,200 |
250 |
1,875 |
80-400 |
0.1-40 |
7.5 |
67 |
6.2 |
460 |
313* |
Copper |
8,950 |
122 |
1,083 |
150 |
55 |
58.0 |
400 |
16.5 |
490 |
-9.6 |
Gold |
19,300 |
78 |
1,064 |
20 |
45 |
44.0 |
315 |
14.2 |
128 |
-34* |
Hafnium |
13,090 |
110 |
2,227 |
300 |
30 |
2.9 |
22 |
5.9 |
145 |
69* |
Indium |
7,310 |
|
157 |
|
|
12.5 |
|
|
|
-51* |
Iridium |
22,500 |
440 |
2,410 |
1,200 |
20 |
19.8 |
147 |
6.8 |
130 |
38* |
Molybdenum |
10,200 |
320 |
2,617 |
300 |
20 |
18.1 |
138 |
5.2 |
276 |
120* |
Niobium |
8,570 |
103 |
2,468 |
220 |
30 |
6.9 |
53 |
7.1 |
280 |
228* |
Palladium |
12,020 |
115 |
1,552 |
250 |
35 |
9.3 |
76 |
11.8 |
245 |
840* |
Platinum |
21,450 |
170 |
1,772 |
80 |
35 |
10.6 |
71 |
9.1 |
132 |
279* |
Rhenium |
21,020 |
460 |
3,180 |
320 |
24 |
5.3 |
71 |
6.6 |
137 |
96* |
Rhodium |
12,440 |
330 |
1,966 |
800 |
25 |
20.9 |
150 |
8.3 |
247 |
168* |
Silver |
10,500 |
78 |
962 |
100 |
35 |
61.4 |
428 |
19 |
235 |
-24* |
Tin |
7,300 |
44 |
232 |
11 |
55 |
8.7 |
73 |
~25 |
220 |
2.4* |
Tungsten |
19,250 |
410 |
3,410 |
1,000 |
2 |
18.4 |
173 |
3.8 |
133 |
80* |
ZirconiumA |
6,506 |
99 |
1,852 |
200 |
16 |
2.3 |
21 |
5.85 |
295 |
160 |
Al-6061T6 |
2,700 |
69 |
582 |
214 |
17 |
25 |
180 |
23.6 |
896 |
19.5 |
C1751-HT |
8,830 |
138 |
1,000 |
700 |
15 |
30 |
240 |
18 |
500 |
-5 |
C715 CuNi |
8,940 |
150 |
1,170 |
300 |
50 |
2.6 |
29 |
16 |
380 |
790 |
D-6 |
8,940 |
130 |
1,100 |
200 |
50 |
~7 |
~70 |
16 |
380 |
22 |
D-20 |
8,900 |
150 |
1,150 |
400 |
40 |
2.3 |
26 |
16 |
380 |
~60 |
Haynes C-22 |
8,690 |
206 |
1,357 |
400 |
65 |
0.9 |
10 |
12.4 |
414 |
590 |
Haynes 188 |
8,980 |
232 |
1,310 |
460 |
53 |
1.0 |
10.8 |
11.8 |
405 |
~1500 |
Haynes 230 |
8,830 |
211 |
1,300 |
400 |
50 |
0.8 |
8.9 |
12.7 |
397 |
~600 |
MWS-800 |
8,100 |
200 |
|
350 |
60 |
0.746 |
9 |
14 |
420 |
~900 |
P-Bronze |
8,860 |
110 |
975 |
200 |
60 |
11.5 |
84 |
17.8 |
380 |
-10.0 |
98/2 CdAg |
8,642 |
55 |
330 |
80 |
15 |
12 |
96 |
30 |
230 |
-19 |
98/2 PbAg |
11,200 |
18 |
304 |
25 |
40 |
4.6 |
32 |
26 |
142 |
0.7 |
63/37-SnPb |
8,340 |
30 |
183 |
40 |
32 |
6.8 |
50 |
22 |
176 |
-3.5 |
96/4-SnAg |
7,500 |
48 |
221 |
55 |
50 |
8.2 |
70 |
20 |
220 |
0.6 |
SS304 |
8,000 |
193 |
1,400 |
300 |
40 |
1.4 |
16 |
17 |
500 |
~3000 |
SS316L |
8,000 |
193 |
1,400 |
300 |
40 |
1.4 |
16 |
16 |
500 |
~2800 |
Ti-6Al-4V |
4,430 |
114 |
1,690 |
900 |
14 |
0.6 |
6.7 |
9.2 |
460 |
170 |
Ti-1100 |
4,500 |
113 |
1,630 |
850 |
15 |
0.6 |
7 |
8.1 |
450 |
~ 150 |
Ti-Beta-C |
4,820 |
105 |
1,560 |
1,200 |
9 |
0.7 |
8 |
8.7 |
450 |
270 |
TZM |
10,160 |
315 |
2,600 |
860 |
6 |
17 |
125 |
4.9 |
280 |
110 |
Udimet 720 |
7,900 |
222 |
1,220 |
1,195 |
13 |
0.7 |
18 |
13.5 |
430 |
540 |
Waspaloy |
8,190 |
230 |
1,330 |
800 |
25 |
0.8 |
11 |
13.6 |
400 |
ferro |
Symbol |
d |
E |
TM |
S |
δ |
σ |
kT |
bT |
CP |
χV |
Above yield strengths of pure elements are typical for quarter-hard temper.
*Published value at unknown field.
ACommercially pure alloy, contains Hf and Fe.
Properties of NMR Probe Dielectric Materials at 300 K
Material |
Dens. |
Youngs mod |
Pois. ratio |
Yield strength |
Elong.
|
Dielect. Const. |
Therm. cond. |
Therm. expan. |
Spec. heat |
Magn. suscept. |
Symbol |
d |
E |
r |
S |
δ |
kd |
kT |
bT |
CP |
χV |
Units |
kg/m3 |
GPa |
|
MPa |
% |
|
W/mK |
10-6 /K |
J/kgK |
10-6 |
99.5Al2O3 |
3,950 |
390 |
0.22 |
240 |
0 |
9.9 |
35 |
8 |
780 |
-14 |
Aurum |
1,330 |
3 |
~0.4 |
80 |
90 |
3.1 |
0.18 |
55 |
1,000 |
-8.9 |
A-JGN3030 |
1,560 |
10 |
0.35 |
130 |
3 |
3.7 |
0.3 |
~35 |
960 |
-6.5 |
A-JCN3030 |
1,450 |
19 |
0.3 |
230 |
2 |
|
0.5 |
~25 |
920 |
-10 |
BeO |
3,010 |
|
|
|
|
7.35 |
|
|
|
-18 |
Bi2O3 |
8,500 |
|
|
|
|
18.2 |
|
|
|
-19 |
Cr2O3 |
5,210 |
|
|
|
|
8 |
|
|
|
~1700 |
E-glass fiber |
2,620 |
100 |
|
3,440 |
4.8 |
6.6 |
~2 |
5.4 |
810 |
15 |
Forsterite |
2,800 |
150 |
0.22 |
120 |
0.1 |
7.8 |
3.3 |
10.5 |
~1000 |
8 |
Kel-F |
2,100 |
1.3 |
~0.45 |
20 |
50 |
2.5 |
0.21 |
60 |
800 |
-11.6 |
Macor |
2,520 |
64 |
0.28 |
80 |
0.2 |
5.9 |
1.7 |
9 |
750 |
-11.7 |
MgO |
3,400 |
250 |
~0.22 |
100 |
0 |
9.6 |
20 |
13.5 |
955 |
-17.8 |
PEEK |
1,300 |
3.8 |
~0.4 |
70 |
60 |
3.3 |
0.24 |
54 |
1,500 |
-9.3 |
PP |
905 |
1 |
~.45 |
23 |
200 |
2.1 |
~.1 |
70 |
|
-9.3? |
PPS |
1,350 |
2.7 |
~0.4 |
60 |
25 |
3 |
~.2 |
50 |
~1200 |
-9.2 |
Y-Zirconia |
6,000 |
220 |
0.25 |
640 |
0.3 |
23 |
3 |
9.5 |
490 |
-8.8 |
Pyrex-7070 |
2,500 |
70 |
0.2 |
40 |
0.1 |
4.0 |
1.3 |
3.3 |
800 |
-11 |
Quartz |
2,250 |
74 |
0.16 |
20 |
0 |
3.8 |
1.4 |
0.5 |
700 |
-11.8 |
SilicaFoam |
770 |
~20 |
– |
~5 |
0.2 |
~1.5 |
~0.1 |
0.5 |
700 |
-3.2 |
SiliconeB |
1,080 |
~.5 |
~0.5 |
7 |
70 |
2.8 |
~0.3 |
<30 |
|
-7.5 |
Si3N4 |
3,250 |
300 |
0.26 |
900 |
0.2 |
7 |
25 |
3.2 |
740 |
-14.0 |
Teflon |
2,200 |
0.4 |
~0.45 |
12 |
300 |
2-2.2 |
0.25+ |
120 |
750 |
-10.5 |
Ultem |
1,270 |
2.7 |
~0.4 |
90 |
60 |
3.15 |
|
55 |
~1300 |
-9.0 |
Vespel |
1,430 |
3.1 |
0.41 |
70 |
90 |
3.5 |
0.33 |
54 |
1,130 |
-9.2 |
Water |
997 |
(2.2) |
– |
0 |
– |
80 |
0.6 |
– |
4,182 |
-9.05 |
Notes: Volume susceptibility χV in SI is related to cgs molar susceptibility χm by: χV =4πd χm /(M.wt.).
Measured χV on commercial material at 7 T, 300 K.
Susceptiblity is much higher at lower fields and lower temperatures for materials containing iron, cobalt, or nickel. Yield strength for metals given for annealed condition with ~10% cold work except for brittle materials.
Elongation given for annealed condition.
Strength of quartz and pyrex varies from 1/3 listed values to three times listed values depending on time under stress and surface conditions.
BDow Corning 96-083
Composition of Selected NMR Probe Materials
Name |
Major Constituents |
Minor Constituents |
Source |
Al-6061T6 |
97Al |
1Mg, .6Si, .3Cu, .2Cr, .3Fe |
|
Haynes C-22 |
60Ni, 22Cr, 13Mo |
3W, 2Co, 3Fe, .007C |
Haynes, Kokomo, IN |
Haynes 188 |
38Co, 22Cr, 22Ni, 14.5W |
2Fe, 1Mn, .3Si, .1C, .07La |
|
Haynes 230 |
55Ni, 22Cr, 14W, 3Co |
2Mo, 2Fe, .5Mn, .4Si, .1C, .02La |
|
MWS-800 |
75Ni, 20Cr |
2.5Al, 2.5Cu |
MWS |
Udimet 710 |
55Ni, 18Cr, 15Co, 5Ti |
3Mo, 2.5Al, 1.5W, .15Fe, .07C |
Special Metals, NY |
C17510 |
97.5Cu |
1.8Ni, 0.4Be, ~0.05(Fe+Co) |
|
C510 |
94.5Cu |
5Sn, .2P, .2Zn, .05Fe |
Phosphor Bronze |
C715 |
67Cu, 30Ni |
0.8Fe, .5Zn, .5Mn, .03Co |
|
C719A |
70Cu, 28Ni, 1.6 Cr |
0.5 Mn, 0.1Si, .03Co, 0.01Fe |
Belmont Metals |
D-20 (revised) |
74Cu, 20Ni, 3Al, 2.5Cr |
0.5Mo, <0.02(Fe+Co+Mn), <0.1% (Mg+Si+Ti+Zr), <0.01% (P+O+H+He), <0.2% other |
Sure Pure |
D-6 |
93.5Cu, 6Ni |
0.38 Cr, <0.005(Fe+Co+Mn) <0.1% (Al+Mg+Si+Ti+Zr) |
Sure Pure |
62/38 SnPb |
62Sn, 38Pb |
.3Sb, .2Bi, .01Fe |
|
SS304 |
68Fe, 19Cr, 9Ni |
2Mn, 1Si, .08C, .045P |
|
Ti-6Al-4V (56401) |
90Ti, 6Al, 4V |
.22Fe, .1O, .08C |
|
Ti-1100 |
86Ti, 6Al, 4Zr |
2.8Sn, .5Si, .4Mo, .02Fe |
|
Ti-Beta-C |
74.5Ti, 8V, 6Cr, 4Zr, 4Mo |
3.2Al, .1Fe, .1O, .02C, .01N |
Alloys International |
TZM |
99+Mo, .5Ti |
.09Zr, .03O, .02C, .01Fe |
Schwarzkoph |
99.5Al2O3 |
99.5Al2O3 |
.5SiO2 |
|
Aurum-JGN3030 |
Polyimide, H, C, N |
30% E-glass |
Mitsui Toatsu Chem., NY |
Aurum-JCN3030 |
Polyimide, H , C, N |
Carbon fiber |
|
Dicor |
60SiO2 , 11MgO, 14K2O |
3MgF2 , 2ZrO2 , 1Al |
Dentsply, York, PA |
E-glass fiber |
54SiO2 , 20CaO, 14Al2O3 |
7B2O3 , Mg, Na, .2Fe, .3F |
|
Forsterite-1330 |
99% 2MgO-SiO2 |
0.25%-1% Al2O3, .1Na, .1B |
Kyocera |
HIP-SN |
98Si3N4 |
2Y2O3 |
ACC Cerama, Sweden |
Kel-f |
CClF3 |
||
Macor |
47SiO2 , 17Al2O3, 12MgO |
9.5K2O, 8.5B2O3 , 3MgF2 |
Corning |
PEEK |
H,C,O |
F |
|
PPS |
Polyphenylene sulfide |
Polymer Corp, ‘Techtron’ |
|
PSZ |
94ZrO2 , 3HfO2 |
3MgO |
|
Pyrex-7070 (elect.) |
72SiO2 , 25B2O3 |
1K2O, 1Al2O3 , .5Li2O, .5Na2O |
Corning |
SilicaFoam |
SiO2 |
.002Fe |
|
Teflon |
C2F4 |
0.05% H2O |
|
Vespel SP-1 |
H, C, N |
F |
DuPont |