The Resonator

31
Mar

New H/F/X/Y Quad MAS for Fluorine

NEWH/F/X/Y Quad MAS
The first probe is a NB 500 MHz probe with a 3 mm sample spinner.  A higher field version with a fast-MAS 1.3 mm spinner is being developed.

Fluorine Quad H/F/X/Y HR-Solids

  • 4 Efficient, high power RF channels
  • Dedicated 19 F and 1H channels for
    1H and 19F operation simultaneously
  • 2 Broadband channels, X/Y
  • Enables 1H and 19F high-power decoupling
    (and 2H decoupling on the X Channel)
  • Fast-MAS 3 mm
  • Extended VT range: NB -150 to +150 °C

                See the poster at the ENC

Acknowledgement:  NIH  R43GM119937

MAS on a 3 mm Doty H/F/X/Y 500 MHz Probe – In the 4 Channel Tuning Mode

Temperature Dependence of  19F NMR  Viton

19F of fluoropolymer, Viton
80 kHz 1H decoupling at 500 MHz
20 kHz MAS, 3 mm rotor, at 76 °C

Expansion of the Region -100 to 220 ppm of the 19F MAS of Viton

Reference the work of S. Ando, R. K. Harris, G. A. Monti, and S.A. Reinsberg, Magnetic Resonance Chemistry 37, 709-720 (1999)

 

About Judy Doty

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